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Please use this identifier to cite or link to this item: http://hdl.handle.net/11334/1070

Title: 部分モル量の熱力学的研究
Other Titles: Partial molar quantities : Die thermodynamische Einfuhrung fur Beziehungsformel zwischen Aktivitat und partiell Molarquantitat
Authors: 佐藤, 均
Author's alias: Sato, H.
Author's Kana: サトウ
Issue Date: 30-Aug-1975
Publisher: 東海学園女子短期大学
Abstract: Some partial molar quantities such as patial molar entalpy, chemical potential etc were investigated by means of mathematical, thermodynamical. derivation in both ideal and non-ideal solution, composed from solvent (1) and solute (2). As practical case, amalgam system (Hg-Na, Hg-Zn, Hg-Tl) and H_2SO_4-H_2O system were chosen for calculationary study. Moreover relation between activity and partial molar quantities was discussed and comparison was performed among ideal, regular and non-ideal solution. The feature consists primarily in mathematical simplification and f. ex. for equilibrium condition in solution we can quite briefly describe this by using one of the three formulars, namely [numerical formula] Finally some essential general formulars could be obtained such as RTd ln ai=-(hi-hi°)dT/T+v_idp-v_I°dp°dμi=d gi=-si dT+li dT/T+v_I°+RTd ln ai etc.
URI: http://hdl.handle.net/11334/1070
Appears in Collections:第10号

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